Redox-promoted associative assembly of metal–organic materials
نویسندگان
چکیده
منابع مشابه
Redox-promoted associative assembly of metal-organic materials.
We develop an associative synthesis of metal-organic materials that combines solid-state metal oxidation and coordination-driven self-assembly into a one-step, waste-free transformation. The methodology hinges on the unique reactivity of ortho-quinones, which we introduce as versatile oxidants for mechanochemical synthesis. Our strategy opens a previously unexplored route to paramagnetic metal-...
متن کاملConversion of CO2 via Visible Light Promoted Homogeneous Redox Catalysis
This review gives an overview on the principles of light-promoted homogeneous redox catalysis in terms of applications in CO2 conversion. Various chromophores and the advantages of different structures and metal centers as well as optimization strategies are discussed. All aspects of the reduction catalyst site are restricted to CO2 conversion. An important focus of this review is the question ...
متن کاملRedox‐Flow Batteries: From Metals to Organic Redox‐Active Materials
Research on redox-flow batteries (RFBs) is currently experiencing a significant upturn, stimulated by the growing need to store increasing quantities of sustainably generated electrical energy. RFBs are promising candidates for the creation of smart grids, particularly when combined with photovoltaics and wind farms. To achieve the goal of "green", safe, and cost-efficient energy storage, resea...
متن کاملAcetic Acid Promoted Redox Annulations with Dual C–H Functionalization
Amines such as 1,2,3,4-tetrahydroisoquinoline undergo redox-neutral annulations with 2-alkylquinoline-3-carbaldehydes as well as the corresponding 4-alkyl isomers and pyridine analogues. These processes involve dual C-H bond functionalization. Acetic acid is used as a cosolvent and acts as the sole promoter of these transformations.
متن کاملRedox-controlled orthogonal assembly of charged nanostructures.
Two of the greatest challenges facing researchers working in the areas of nanoscience and nanotechnology are the following: the development of straightforward methods for organizing structures with sub-100 nm dimensions on surfaces into functional architectures and then interfacing such structures with macroscopically addressable components in predefined ways. Although “self-assembly” is often ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemical Science
سال: 2016
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c5sc02214b